منابع مشابه
Paramagnetic relaxation of nuclear singlet states.
Nuclear singlet states often display lifetimes that are much longer than conventional nuclear spin relaxation times. Here we investigate the effect of dissolved paramagnetic species on the singlet relaxation of proton pairs in solution. We find a linear correlation between the singlet relaxation rate constant T and the longitudinal relaxation rate constant T. The slope of the correlation depend...
متن کاملResonance Paramagnetic Relaxation and Alignment of Small Grains.
We show that the energy-level splitting that arises from grain rotation ensures that paramagnetic dissipation acts at its maximum rate, i.e., the conditions for paramagnetic resonance are automatically fulfilled. We refer to this process as "resonance relaxation." The differences between the predictions of classical Davis-Greenstein relaxation and resonance relaxation are most pronounced for gr...
متن کاملGeneral treatment of paramagnetic relaxation enhancement associated with translational diffusion.
A theory of nuclear spin relaxation in isotropic liquids for nuclear spins interacting with electron spins, residing in other molecules (the outer-sphere relaxation), is presented. The approach, valid outside of the Redfield limit for electron spin relaxation, is an extension of the Swedish slow motion theory [Benetis et al., Mol. Phys. 48, 329 (1983); Nilsson and Kowalewski, J. Magn. Reson. 14...
متن کاملEfficiency of paramagnetic relaxation enhancement in off-resonance rotating frame.
Transferring from laboratory frame to off-resonance rotating frame for the (1)H spin can compensate the relaxivity loss for paramagnetic agents at the magnetic field strength higher than 3 Tesla and enhance water relaxation rate constant significantly. A comprehensive theory for calculating the relaxation rate constants in the off-resonance rotating frame is described. This theory considers the...
متن کاملEnhancement of Paramagnetic Relaxation by Photoexcited Gold Nanorods
Electron spin resonance (ESR) spectroscopy was used to investigate the switchable, light-dependent effects of gold nanorods (GNRs) on paramagnetic properties of nitroxide spin probes. The photoexcited GNRs enhanced the spin-spin and spin-lattice relaxations of nitroxide spin probes. It was shown that molecular oxygen plays the key role in this process. Our results demonstrate that ESR is a powe...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1948
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed025p296.2